Preparation, Characterization, and Hydro-Stability Assessment of Sodium Glyceroxide
DOI:
https://doi.org/10.26534/kimika.v35i1.17-23Keywords:
sodium glyceroxide, sodium 2,3-dihydroxypropan-1-olate, biodiesel, catalystAbstract
The present study described the successful preparation, characterization (XRD and FTIR Spectroscopy), and hydro-stability assessment of sodium glyceroxide (NaOGl), a compound commonly used as a catalyst in the preparation of biodiesel with promising new application in the selective synthesis of monolaurin and monoacylglycerides (MAGs). NaOGl is a crystalline solid that is difficult to handle under “wet” conditions because of its high hygroscopicity and high reactivity with water in air and in solution. The data presented here provides insights into the relevant physicochemical parameters of NaOGl and an analysis of the extent of the working conditions involving NaOGl as a reactant.
References
Batovska DI, Todorova IT, Tsvetkova IV, Najdenski HM. Antibacterial study of the medium chain fatty acids and their 1-monoglycerides: individual effects and synergistic relationships. Pol J Microbiol. 2009;58(1):43–47. https://pubmed.ncbi.nlm.nih.gov/19469285/
Bergsson G, Arnfinnsson J, Karlsson SM, Steingrímsson O, Thormar H. In vitro inactivation of Chlamydia trachomatis by fatty acids and monoglycerides. Antimicrob Agents Chemother. 1998 September; 42(9):2290–2294. https://doi.org/10.1128/AAC.42.9.2290
Bergsson G, Arnfinnsson J, Steingrímsson O null, Thormar H. In vitro killing of Candida albicans by fatty acids and monoglycerides. Antimicrob Agents Chemother. 2001 November; 45(11):3209–3212. https://journals.asm.org/doi/10.1128/aac.45.11.3209-3212.2001
Bergsson G, Steingrímsson O, Thormar H. Bactericidal effects of fatty acids and monoglycerides on Helicobacter pylori. Int J Antimicrob Agents. 2002 October; 20(4):258–262. https://doi.org/10.1016/s0924-8579(02)00205-4
Bergsson G, Steingrímsson O, Thormar H. In vitro susceptibilities of Neisseria gonorrhoeae to fatty acids and monoglycerides. Antimicrob Agents Chemother. 1999 November; 43(11):2790–2792. https://doi.org/10.1128/AAC.43.11.2790
Bradley D, Levin E, Rodriguez C, Williard PG, Stanton A, Socha AM. Equilibrium studies of canola oil transesterification using a sodium glyceroxide catalyst prepared from a biodiesel waste stream. Fuel Process Technol. 2016 Jun 1;146:70–75. https://doi.org/10.1016/j.fuproc.2016.02.009
Cayona R, Yu G. Selective synthesis of monolaurin: a preliminary investigation. Philipp J Sci. 2023;152(3):983-988. https://doi.org/10.56899/152.03.18
Conley AJ, Kabara JJ. Antimicrobial action of esters of polyhydric alcohols. Antimicrob Agents Chemother. 1973 November; 4(5):501–506. https://doi.org/10.1128/AAC.4.5.501
Esipovich A, Rogozhin A, Danov S, Belousov A, Kanakov E. The structure, properties and transesterification catalytic activities of the calcium glyceroxide. Chem Eng J. 2018 May; 339:303–316. https://doi.org/10.1016/j.cej.2018.01.142
Fairbourne A, Gibson GP, Stephens DW. LX. The partial esterification of polyhydric alcohols. Part XI. The five methyl ethers of glycerol and related compounds. J Chem Soc Resumed. 1931 Jan 1;(0):445–458. https://pubs.rsc.org/en/content/articlelanding/1931/jr/jr9310000445
Downloads
Additional Files
Published
Issue
Section
License
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).