Possible cobalt-cobalt bridging by a hemiacetal in the dinuclear cobalt complex bearing the ligand bis(3-(2-Pyridylmethyleneamino)phenyl) sulfone

  • Armando M. Guidote Department of Chemistry, Faculty of Science & Technology, Sophia University, Tokyo Japan Department of Chemistry, School of Science & Engineering, Ateneo de Manila University, Loyola Heights, Quezon City Philippines
  • Tomoko Imajo Department of Chemistry, Faculty of Science & Technology, Sophia University, Tokyo
  • Yoshiro Masuyama Department of Chemistry, Faculty of Science & Technology, Sophia University, Tokyo
Keywords: dinuclear, cobalt, complex, synthesis

Abstract

A dinuclear cobalt complex bearing the ligand bis(3-(2-pyridylmethyleneamino)phenyl) sulfone (BPMAPS) was prepared. It is proposed that the structure of this is [Co2(BPMAPS)(m-OAcM)2(hemi-Et)]PF6 wherein the cobalt centers are bridged by two carboxylato groups in m-fashion and a hemiacetal with an ethoxy group (hemi-Et). This proposal is based on the similarity of the FT-IR, UV-Vis, and FAB-MS results with the crystallographically characterized dinuclear manganese complex [Mn2(BPMAPS)(m-OAc)2(hemi-Me)]PF6, and elemental analysis results.

How to Cite
Guidote, A. M., Imajo, T., & Masuyama, Y. (1). Possible cobalt-cobalt bridging by a hemiacetal in the dinuclear cobalt complex bearing the ligand bis(3-(2-Pyridylmethyleneamino)phenyl) sulfone. KIMIKA, 20(1), 17-20. https://doi.org/10.26534/kimika.v20i1.17-20
Section
Research Articles